期刊論文
| 學年 | 114 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2025-12-03 |
| 作品名稱 | Oxygenated Carbon Electrocatalysts for Chlorine Evolution Reaction |
| 作品名稱（其他語言） | |
| 著者 | Yajie Shu; Jiapeng Ji; Junxian Liu; Zhixian Mao; Shan Chen; Ming Zhou; Kaicai Fan; Dongchen Qi; Cheng-Hao Chuang; Zhengju Zhu; Yun Wang; Porun Liu; Haimin Zhang; Huajie Yin; Huijun Zhao |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Journal American Chemical Society 147(48), p.44293-44302 |
| 摘要 | The chlor-alkali process plays an irreplaceable role in global chemical industry, but relies heavily on RuO2 (or IrO2)/TiO2-based dimensionally stable anodes, hindering sustainability and new applications. We report a facile oxygenation activation approach to create apt oxygen groups on commercial carbon black and carbon cloth. Our experimental and theoretical studies reveal that creation of carbonyl, cyclic ether, and carboxyl groups on the graphitic plane edges gives commercial carbon materials superb chlorine evolution reaction activity (overpotential: 204 mV at 1 A cm–2), selectivity (average Faraday efficiency: 99.6 ± 1.3%), and stability (stable operation for 100 h at 0.5 A cm–2), which is comparable to or better than the benchmark RuO2 and dimensionally stable anodes. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0002-7863; 1520-5126 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/129583 ) |