期刊論文
| 學年 | 113 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2025-06-05 |
| 作品名稱 | D-orbital-modulated ruthenium embedded within functionalized hollow MXene networks for enhanced hydrazine-assisted hydrogen production |
| 作品名稱（其他語言） | |
| 著者 | Thanh Hai Nguyen; Duy Thanh Tran; Deepanshu Malhotra; Phan Khanh Linh Tran; Van An Dinh; Thi Thuy Nga Ta; Chung-Li Dong; Nam Hoon Kim; Joong Hee Lee |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Small 21(22), 2502553 |
| 摘要 | Electrochemical green hydrogen production via water splitting is an attractive and sustainable pathway; however, the sluggish kinetics of anodic oxygen evolution reaction is still a critical challenge. In this study, an effective electrocatalyst engineering approach is demonstrated by preparing an innovative hybrid of ruthenium d-orbitals-regulated nanoclusters embedding within functionalized hollow Ti3C2 MXene networks (Ru0.91Ni0.09-N/O-Ti3C2) to promote the hydrazine-assisted hydrogen production. A specific charge redistribution is revealed, locally concentrating at interfaces derived from stable Ru(Ni)-N/O-Ti coordination and d–p orbital hybridization. The charge transfer effect from Ni to Ru within Ru0.91Ni0.09 structure and Ru0.91Ni0.09 to N/O-Ti3C2 tailors electronic features of Ru sites to enable reasonable adsorption/desorption toward reactant intermediates. The Ru0.91Ni0.09-N/O-Ti3C2 requires an overpotential of only 29.3 mV for cathodic hydrogen evolution and a low potential of −29.9 mV for anodic hydrazine oxidation to reach 10 mA cm−2, showing excellent stability. The hydrazine-assisted hydrogen production system based on Ru0.91Ni0.09-N/O-Ti3C2 electrodes delivers small cell voltages of 0.02 V at 10 mA cm−2 and 0.92 V at industrial current level of 1.0 A cm−2. This work may open a new electrocatalysis strategy from lab scale to industry for robust and efficient green hydrogen production. |
| 關鍵字 | d-orbital-modulated Ru sites; hybrid electrocatalyst; hydrazine-assisted hydrogen production; porous functionalized MXene |
| 語言 | en |
| ISSN | 1613-6810; 1613-6829 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 是 |
| 國別 | DEU |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/129486 ) |