期刊論文
| 學年 | 113 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2025-06-24 |
| 作品名稱 | Spray-dried nanoarchitectonics of SiOx/C composite as a high-performance anode material for lithium-ion batteries |
| 作品名稱（其他語言） | |
| 著者 | Yu-Sheng Hsiao; Jen-Hsien Huang; Tzu-Hsien Hsieh; Lin-Yang Weng; Sheng-Wei Liao; Yin-Cheng Yen; Wei Kong Pang; Shih-Chieh Hsu; Huei Chu Weng; Yu-Ching Huang |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Journal of the Taiwan Institute of Chemical Engineers 184, 106243 |
| 摘要 | Background Silicon monoxide (SiOx, 0 < x < 2) faces limitations in commercial applications due to its poor electrical conductivity and significant volume expansion during operation. Methods In this study, SiOx-based composites (C-SiOx) integrated with graphite (GF), soft carbon (SC), and asphalt (AP) were prepared using a spray-drying method followed by high-temperature carbonization. Moreover, the C-SiOx electrode was further modified with a thin Al2O3 layer via atomic layer deposition (ALD). To practically assess the potential application of the as-prepared C-SiOx composite, soft-packed lithium-ion batteries (LIBs) incorporating C-SiOx as the anode and LiNi0.5Mn1.5O4 (LNMO) as the cathode, were fabricated. Significant findings The blended GF and SC within the C-SiOx microspheres significantly enhance electrical conductivity and act as buffers to mitigate volume changes during the charge/discharge process. Additionally, the AP forms a thin, amorphous carbon coating on the SiOx surface during the thermal annealing process, improving ionic transport. The ALD-coated Al2O3 effectively isolates the electrode from direct contact with the electrolyte, thereby suppressing undesired side reactions. As a result, the full LIB utilizing the Al2O3-modified C-SiOx anode exhibits milder gassing behavior, a lower expansion rate, and improved cyclability. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 1876-1089; 1876-1070 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/129426 ) |