期刊論文
| 學年 | 112 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2024-02-26 |
| 作品名稱 | Red phosphorus grafted high-index (116) faceted anatase TiO2 for Z-scheme photocatalytic pure water splitting |
| 作品名稱（其他語言） | |
| 著者 | Yukun Zhu; Jun Ren; Guiqing Huang; Chung-Li Dong; Yu-Cheng Huang; Ping Lu; Hua Tang; Yiming Liu; Shaohua Shen; Dongjiang Yang |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Advanced Functional Materials 34(9), 2311623 |
| 摘要 | Red phosphorus (RP) is an emerging visible-light-responsive photocatalyst, yet the rapid charge recombination has limited photocatalytic hydrogen production activity. In this work, a Z-scheme heterostructure with RP nanolayer coated on high-index (116) faceted anatase TiO2 nanoparticles (TiO2@RP) is designed and fabricated via chemical vapor deposition. Compared with pristine TiO2 and RP, the optimized TiO2@RP Z-scheme heterostructure exhibits a significantly boosted photocatalytic activity for pure water splitting, with hydrogen evolution rate reaching 12.9 µmol·h−1, under simulated solar light irradiation. The strong interfacial interaction and staggered band alignment between (116) faceted TiO2 and RP result in the formation of built-in electric field, which can drive the directional charge migration from the conduction band (CB) of TiO2 to the valance band (VB) of RP under light irradiation, with photoelectrons and holes of high redox ability maintained at the CB of RP and the VB of TiO2, respectively. This well-designed heterostructure greatly promotes photogenerated charge separation and migration via a direct Z-scheme charge transfer pathway. |
| 關鍵字 | high-index facet; red phosphorus; titanium oxide; water splitting; Z-scheme heterostructures |
| 語言 | en_US |
| ISSN | 1616-301X ;1616-3028 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 是 |
| 國別 | DEU |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/127598 ) |