期刊論文
| 學年 | 113 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2024-08-07 |
| 作品名稱 | Electrocatalytic ammonia oxidation to nitrite and nitrate with NiOOH-Ni |
| 作品名稱（其他語言） | |
| 著者 | Hanwen Liu; Cheng-Jie Yang; Chung-Li Dong; Jiashu Wang; Xin Zhang; Andrey Lyalin; Tetsuya Taketsugu; Zhiqi Chen; Daqin Guan; Xiaomin Xu; Zongping Shao; Zhenguo Huang |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Advanced Energy Materials 14(42), 2401675 |
| 摘要 | Ammonia electrooxidation in aqueous solutions can be a highly energy-efficient process in producing nitrate and nitrite while generating hydrogen under ambient conditions. However, the kinetics of this reaction are slow and the role of catalyst in facilitating ammonia electrooxidation is not well understood. In this study, a high-performance NiOOH-Ni catalyst is introduced for converting ammonia into nitrite with Faraday efficiency of up to 90.4% and nitrate production rate of 1 mg h−1 cm−2. By employing Operando techniques, the role of NiOOH catalyst is elucidated in the dynamic electrooxidation of ammonia. Density functional theory (DFT) calculations support experimental observations and reveal the mechanism of the electrochemical oxidation of ammonia to nitrite and nitrate. Overall, this research contributes to the development of a cost-effective and highly efficient catalyst for large-scale ammonia electrolysis, while shedding light on the underlying mechanism of the NiOOH catalyst in ammonia electrooxidation. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 1614-6832; 1614-6840 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 是 |
| 國別 | DEU |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/127588 ) |