期刊論文
| 學年 | 109 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2021-04-27 |
| 作品名稱 | Ligand‐promoted Cooperative Electrochemical Oxidation of Bio‐alcohol on Distorted Cobalt Hydroxides for Bio‐hydrogen Extraction |
| 作品名稱（其他語言） | |
| 著者 | Chen Deng；Kuang-Hsu Wu；Xinxin Lu；Soshan Cheong；Richard Tilley；Chao-Lung Chiang；Yu-Chang Lin；Yan-Gu Lin；Wensheng Yan；Jason Scott；Rose Amal；Da-Wei Wang |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | ChemSusChem 14(12), p.2612-2620 |
| 摘要 | Hydrogen is increasingly viewed as a game-changer in the clean energy sector. Renewable hydrogen production from water is industrialized by integrating water electrolysis and renewable electricity, but the current cost of water-born hydrogen remains high though. An ideal scenario would be to produce value-added chemicals along with hydrogen so the cost can be partially offset. Herein, facilitated bio-hydrogen extraction and biomass-derived chemical formation from sugar-derived 5-hydroxymethyfurfural (HMF) were achieved via the in-situ transformation of cobalt-bound electrocatalysts. The cyanide-bound cobalt hydroxide exhibited a low voltage at 1.55 V at 10 mA cm−2 for bio-hydrogen production, compared with an iridium catalyst (1.75 V). The interaction between the biomass intermediate and the cyanide ligand is suggested to be responsible for the improved activity. |
| 關鍵字 | |
| 語言 | en_US |
| ISSN | |
| 期刊性質 | 國外 |
| 收錄於 | SCI SSCI Scopus |
| 產學合作 | |
| 通訊作者 | Kuang-Hsu Wu, Da-Wei Wang |
| 審稿制度 | 是 |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/127734 ) |