期刊論文
| 學年 | 110 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2022-07-18 |
| 作品名稱 | Atomically dispersed Janus nickel sites on red phosphorus for photocatalytic overall water splitting |
| 作品名稱（其他語言） | |
| 著者 | Menglong Wang; Shuai Xu; Prof. Zhaohui Zhou; Prof. Chung-Li Dong; Dr. Xu Guo; Jeng-Lung Chen; Dr. Yu-Cheng Huang; Prof. Shaohua Shen; Prof. Yubin Chen; Prof. Liejin Guo; Prof. Clemens Burda |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Angewandte Chemie 61(29), e202204711 |
| 摘要 | Single-atom nickel catalysts hold great promise for photocatalytic water splitting due to their plentiful active sites and cost-effectiveness. Herein, we adopt a reactive-group guided strategy to prepare atomically dispersed nickel catalysts on red phosphorus. The hydrothermal treatment of red phosphorus leads to the formation of P−H and P−OH groups, which behave as the reactive functionalities to generate the dual structure of single-atom P−Ni and P−O−Ni catalytic sites. The produced single-atom sites provide two different functions: P−Ni for water reduction and P−O−Ni for water oxidation. Benefitting from this specific Janus structure, Ni-red phosphorus shows an elevated hydrogen evolution rate compared to Ni nanoparticle-modified red phosphorus under visible-light irradiation. The hydrogen evolution rate was additionally enhanced with increased reaction temperature, reaching 91.51 μmol h−1 at 70 °C, corresponding to an apparent quantum efficiency of 8.9 % at 420 nm excitation wavelength. |
| 關鍵字 | Nickel;Photocatalysis;Red Phosphorus;Single-Atom Catalysts;Water Splitting |
| 語言 | en |
| ISSN | 1521-3773; 1433-7851 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 是 |
| 國別 | DEU |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/124104 ) |