期刊論文
學年 | 107 |
---|---|
學期 | 2 |
出版(發表)日期 | 2019-05-01 |
作品名稱 | Red phosphorus decorated and doped TiO2 nanofibers for efficient photocatalytic hydrogen evolution from pure water |
作品名稱(其他語言) | |
著者 | Y. Zhu; J. Li; C. L. Dong; J. Ren; Y. C. Huang; D. Zhao; R. Cai; X. Yang; C. Lv; W. Theis; Y. Bu; W. Han; S. Shen; D. Yang |
單位 | |
出版者 | |
著錄名稱、卷期、頁數 | Applied Catalysis B: Environmental 255, 117764 |
摘要 | In this study, we report a facile strategy to prepare a new class of red phosphorus (RP) decorated and doped TiO2 (A: anatase and B: TiO2(B)) nanofibers with boosted photocatalytic hydrogen evolution reaction (HER) performance from pure water. The optimized TiO2(B)/RP and TiO2(A)/RP heterostructure exhibits significantly enhanced photocatalytic performances, with HER rate reaching 11.4 and 5.3 μmol h−1, respectively. The optical absorption of TiO2 is significantly extended to the visible light region after decoration of RP. And more oxygen vacancies (VO) were introduced by phosphorus doping in the TiO2(B)/RP than TiO2(A)/RP. The theoretical calculations illustrate the formation of VO can decrease the ratio of effective masses of electron to hole, which gives rise to promoted photoinduced charge separation and transfer. These results suggest that the boosted photocatalytic HER performance should be mainly attributed to the synergetic enhancement in light harvesting and charge separation enabled by RP deposition and P5+ doping. |
關鍵字 | Red phosphorus;Titanium oxide;Photocatalytic hydrogen evolution;Pure water splitting |
語言 | en |
ISSN | 1873-3883 |
期刊性質 | 國外 |
收錄於 | SCI |
產學合作 | |
通訊作者 | |
審稿制度 | 是 |
國別 | USA |
公開徵稿 | |
出版型式 | ,電子版 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/118670 ) |