期刊論文
| 學年 | 85 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 1996-09-20 |
| 作品名稱 | Pressure-induced electron transfer in quasi-molecular solids |
| 作品名稱（其他語言） | |
| 著者 | Hsueh, H. C.; W. C. K. Poon; H. Vass; J. Crain |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Europhysics Letters 35(9), pp.689-694 |
| 摘要 | A combination of Raman scattering and synchrotron X-ray powder diffraction on Group-V metal triiodides (XI3, X = As,Sb,Bi) has revealed a continuous isostructural transition from a molecular solid to a two-dimensional layered crystal under high pressure. The loss of molecular identity proceeds by gradual pressure-induced electron transfer from intramolecular to intermolecular bonds and suppression of sp3 hybridisation. Initial pressure increase has the effect of destroying molecular units while continued compression enhances intralayer cohesion. These two effects give rise to a non-monotonic pressure variation of the X-I bond-stretching frequency. |
| 關鍵字 | |
| 語言 | en |
| ISSN | |
| 期刊性質 | 國外 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 0 |
| 國別 | GBR |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/107885 ) |