期刊論文
| 學年 | 103 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2015-07-01 |
| 作品名稱 | Thermal analyses of dye Disperse Red 1 grafted onto silica nanoparticles |
| 作品名稱（其他語言） | |
| 著者 | Chao-Ching Chang; Feng-Hsi Huang; Zi-Min Lin; Liao-Ping Cheng |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Journal of Coatings Technology and Research, 12(4), pp.731-738 |
| 摘要 | Dye-grafted silica nanoparticles (GSiO2 ) were synthesized via a dual-step process involving, first, attachment of the organic dye Disperse Red 1 (DR1) to the coupling agent, 3-isocyanatopropyltri- ethoxysilane, by means of urethane bonds, and then grafting of the silylated-DR1 onto silica nanoparticles (6 nm) prepared by hydrolysis and condensation of tetraethoxysilane in a sol–gel process. Dye-adsorbed silica nanoparticles (DSiO 2 ) were also prepared for comparison, for which DR1 was bound only physically to silica instead of covalent bonds. The thermal behaviors of the formed GSiO 2 and DSiO 2 were examined by means of differential scanning calorime- try and thermal gravimetric analysis. The results showed that both the particle size and silica content have significant effects on the thermal behaviors of the dye-adsorbed and dye-grafted silica. Moreover, crys- talline DR1 lost significantly its crystallinity after being adsorbed on silica, and became virtually amorphous after being grafted onto silica. The formed particles were UV-cured with a multifunctional acrylic mono- mer to yield color coatings on glass substrates. UV– visible spectra indicated that brightness and color saturation of the coating comprising GSiO 2 could be maintained better than that comprising DSiO 2 after heat treatment at 280C. |
| 關鍵字 | |
| 語言 | en_US |
| ISSN | |
| 期刊性質 | 國內 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 是 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/110265 ) |