期刊論文
| 學年 | 103 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2014-10-01 |
| 作品名稱 | Diffusiophoresis of a pH-regulated, zwitterionic polyelectrolyte in a solution containing multiple ionic species |
| 作品名稱（其他語言） | |
| 著者 | Tseng, Shiojenn; Su, Chun-Yuan; Hsu, Jyh-Ping |
| 單位 | 淡江大學數學學系 |
| 出版者 | Kidlington: Pergamon Press |
| 著錄名稱、卷期、頁數 | Chemical Engineering Science 118, pp.164-172 |
| 摘要 | The diffusiophoresis of a pH-regulated, zwitterionic polyelectrolyte (PE) simulating entities such as DNAs, proteins, and synthetic polymeric particles in a solution containing multiple ionic species is modeled theoretically. The results of numerical simulation reveal that the diffusiophoretic behavior of the PE is influenced significantly by its physicochemical properties, the solution pH, the bulk salt concentration, and the types of ionic species. In particular, both the magnitude and the sign of the PE mobility are influenced appreciably by the bulk salt concentration and the types of ionic species. We show that the induced electric field coming from the applied concentration gradient is weakened by the movement of H+ and OH−. This phenomenon is more appreciable when pH is away from the isoelectric point of a PE. The results obtained provide valuable and necessary information for the design of diffusiophoresis devices. |
| 關鍵字 | Diffusiophoresis;Polyelectrolyte;pH-regulated and zwitterionic;Multiple ionic species |
| 語言 | en |
| ISSN | 0009-2509 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | Hsu, Jyh-Ping |
| 審稿制度 | 是 |
| 國別 | GBR |
| 公開徵稿 | |
| 出版型式 | ,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/102861 ) |