期刊論文
| 學年 | 103 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2015-03-01 |
| 作品名稱 | Photofunctional Platinum Complexes Featuring N-heterocyclic Carbene-Based Pincer Ligands |
| 作品名稱（其他語言） | |
| 著者 | Lin, Wan-Jung; Abbas Raja Naziruddin; Chen, Yu-Hsuan; Sun, Bian-Jian; Chang, Hsiu Hwa; Wang, Wen-Jwu; Hwang, Wen-Shu |
| 單位 | 淡江大學化學學系 |
| 出版者 | Weinheim: Wiley - V C H Verlag GmbH & Co. KGaA |
| 著錄名稱、卷期、頁數 | Chemistry – An Asian Journal 10(3), pp.728-739 |
| 摘要 | Photoactive platinum complexes of stoichiometry [Pt(RCCCR)L]0/+ (R=Me, nBu and L=[BOND]CN, [BOND]C≡CPh, [BOND]N≡CCH3, [BOND]Py, [BOND]CO) featuring pincer-type bis N-heterocyclic carbene (NHC) ligands (RCCCR) were synthesized. Organometallic syntheses of these complexes are facile and achievable through standard laboratory procedures. Control of intermolecular Pt⋅⋅⋅Pt interaction, π–π stacking, and emission tuning is achieved through suitable choice of the NHC-wingtip substituent (R) and the auxiliary ligand (L). Exposure to specific volatile organic compounds (VOCs) or mechanical grinding triggers changes in emission colors, which render these complexes photofunctional. Solid-state structures and photoluminescence results are described herein. |
| 關鍵字 | |
| 語言 | en_US |
| ISSN | 1861-471X |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | Hwang, Wen-Shu |
| 審稿制度 | 否 |
| 國別 | DEU |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/101009 ) |