會議論文
| 學年 | 103 |
|---|---|
| 學期 | 1 |
| 發表日期 | 2015-01-26 |
| 作品名稱 | Oxy-carbonylation Reaction Path Synthesis and Its Conceptual Process Design for Manufacturing the Pesticide Carbaryl |
| 作品名稱（其他語言） | |
| 著者 | 陳錫仁;戴邱惠;張創堯 |
| 作品所屬單位 | 化學工程與材料工程學系暨研究所 |
| 出版者 | |
| 會議名稱 | CCECP 2015, 3rd Annual International Conference on Chemistry, Chemical Engineering and Chemical Process |
| 會議地點 | Hotel Fort Canning, Singapore. |
| 摘要 | Four issues in green chemistry are a search for: (1) alternative feedstocks, (2) green solvents, (3) new synthesis pathways, and (4) inherently safer chemistry. In this paper, we propose a novel synthesis pathway to the production of Carbaryl that avoids hazardous intermediates and hazardous by-products by way of an addition reaction, which is considered as one of the atom-economic reactions. This is accomplished by using α-naphthol, methyl amine, carbon monoxide and oxygen (that is, oxy-carbonylation) as raw materials,
 
 This approach appears to be an excellent synthesis route to produce Carbaryl, with only water as by-product. In the research, we also present all possible synthesis pathways of Carbaryl. The thermodynamic constraints in regard to spontaneity as well as atom economy and safety were provided. In order to extend the green chemistry to green engineering, we also propose a conceptual process design scheme for the manufacture of Carbaryl. |
| 關鍵字 | |
| 語言 | en_US |
| 收錄於 | |
| 會議性質 | 國際 |
| 校內研討會地點 | |
| 研討會時間 | 20150126~20150127 |
| 通訊作者 | 陳錫仁 |
| 國別 | SGP |
| 公開徵稿 | Y |
| 出版型式 | 電子版 |
| 出處 | CCECP 2015, 3rd Annual International Conference on Chemistry, Chemical Engineering and Chemical Process |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/100709 ) |