期刊論文

標題 Kinetics of Sodium Borohydride Hydrolysis Reaction for Hydrogen Generation
學年 97
學期 1
出版(發表)日期 2008/11/01
作品名稱 Kinetics of Sodium Borohydride Hydrolysis Reaction for Hydrogen Generation
作品名稱(其他語言)
著者 Hung, Ai-jen; Tsai, Shing-fen; Hsu, Ya-yi; Ju, Jie-ren; Chen, Yih-hang; Yu, Cheng-ching
單位 淡江大學化學工程與材料工程學系
出版者 Elsevier
著錄名稱、卷期、頁數 International Journal of Hydrogen Energy 33(21), pp.6205-6215
摘要 In this work, a ruthenium catalyst was prepared for hydrogen generation from the hydrolysis reaction of an alkaline sodium borohydride solution. The reactions were carried out in a batch reactor at temperatures of 10, 30, 40 and 60 °C for at least 70% conversion or 500 min, whichever came first. The experimental data was fitted to the following three kinetic models: zero-order, first-order, and Langmuir–Hinshelwood. The results indicate that the Langmuir–Hinshelwood model gives a reasonable description of the hydrogen generation rate over the entire temperature range studied as well as the time spans of the experiments. The zero-order model gives good behavior description only at relatively low temperature, i.e. 10 °C. The first-order model works fairly well for a temperature range up to 30 °C.
關鍵字 Kinetics;Sodium borohydride;Hydrolysis reaction;Hydrogen generation
語言 英文
ISSN 0360-3199
期刊性質 國外
收錄於
產學合作
通訊作者
審稿制度
國別 英國
公開徵稿
出版型式 ,紙本