期刊論文
| 學年 | 95 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2006-11-01 |
| 作品名稱 | Graft polymerization of vinyl acetate onto granular starch: Comparison on the potassium persulfate and ceric ammonium nitrate initiated system |
| 作品名稱（其他語言） | |
| 著者 | Lai, S. M.; 董崇民; Don, Trong-ming; Liu, Y. H.; Chiu, Wen-yen |
| 單位 | 淡江大學化學工程與材料工程學系 |
| 出版者 | Wiley-Blackwell |
| 著錄名稱、卷期、頁數 | Journal of Applied Polymer Science 102(3), pp.3017-3027 |
| 摘要 | This work was undertaken to discuss in depth the vital differences in the morphological development during synthesis, and properties of starch-g-poly-(vinyl acetate) copolymers using two different initiators, potassium persulfate (KPS) and ceric ammonium nitrate (CAN). KPS-initiated system gave relatively low values of grafting ratio and grafting efficiency, indicating a great tendency for the formation of poly(vinyl acetate) homopolymer (PVAc). Yet, higher values were seen for the CAN-initiated system. Transmission electron microscope observations indicated a relatively broad distribution of latex particles for the KPS-initiated system. The surface potential of latex particles was about −3.5 mV, which turned out to be insufficient to maintain stability of latex particles. On the other hand, a uniform particle size distribution was found for the CAN-initiated system, as the surface potential of latex particles was 21.5 mV. Moreover, radicals on starch molecules were generated directly through a redox reaction with positively charged ceric ion. The hydrophobic PVAc chains were thus grafted on starch, resulting in an amphiphilic graft copolymer, which provides a sufficient stabilization degree as a role of surfactant to render a relatively uniform distribution of latex particles. The synthesized starch-g-poly(vinyl acetate) copolymers were further converted to starch-g-poly(vinyl alcohol) through saponification, which were subjected to evaluations regarding the biodegradation and cell culture capability. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3017–3027, 2006 |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0021-8995 |
| 期刊性質 | 國內 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/44121 ) |