期刊論文
| 學年 | 94 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2005-12-01 |
| 作品名稱 | Nucleophilic Cleavage of Crosslinked Polysiloxanes to Cyclic Siloxane Monomers: Mild Catalysis by a Designed Polar Solvent System |
| 作品名稱（其他語言） | |
| 著者 | 張正良; Chang, Cheng-liang; Lee, Howard Shih-jen; Chen, Cheng-kwo |
| 單位 | 淡江大學化學工程與材料工程學系 |
| 出版者 | Springer |
| 著錄名稱、卷期、頁數 | Journal of Polymer Research 12(6), pp.433-438 |
| 摘要 | The solvent effect on the cyclic compound formation in the base-catalyzed aminolysis reaction of room temperature vulcanized polydimethylsiloxane networks under ambient temperature was investigated. The complete dissolution time of the silicone rubber in the less polar solvent system was longer which is attributed to the internal diffusion resistance for the penetration of the activated nucleophiles in the inherent hydrophobic polysiloxane networks. The main products were cyclic oligomers in the polar solvent systems. The reaction rate of aminolysis was proved to be faster than that of alcoholysis with the aid of a model compound under the reaction conditions designed. |
| 關鍵字 | alcoholysis;aminolysis;base catalyst;polydimethylsiloxane networks |
| 語言 | en |
| ISSN | 1022-9760 |
| 期刊性質 | 國外 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | NLD |
| 公開徵稿 | |
| 出版型式 | ,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/44188 ) |