期刊論文
學年 | 100 |
---|---|
學期 | 1 |
出版(發表)日期 | 2011-10-25 |
作品名稱 | Fabrication, microstructural analysis, and properties of poly(methyl methacrylate)/calcium carbonate particulates nanocomposites |
作品名稱(其他語言) | |
著者 | Lin, Ching-bin |
單位 | 淡江大學機械與機電工程學系 |
出版者 | Hoboken: John Wiley & Sons, Inc. |
著錄名稱、卷期、頁數 | Advances in Polymer Technology 31(4), pp.280–291 |
摘要 | The poly(methyl methacrylate) (PMMA)/nanometer-scaled calcium carbonate particulate nanocomposites prepared by means of the gas-synthesis was investigated. PMMA absorbed the saturated solvent mixture (the ratio of calcium chloride dehydrate and methanol at 1.5, 4.5, and 6.0 g/100 g) at 40–60° and then desorbed the methanol completely and then CO2 gas diffused into the desorbed completely in specimens for 48 h at 60°, approximately 30-nm calcium carbonate particulates were precipitated evenly to distribute in the PMMA matrix. The content of calcium carbonate particulates decreases with increasing concentration of the saturated solvent mixture. The transmittance of the nanocomposites decreases with the increasing content of calcium carbonate particulates and the cutoff wavelength of transmittance is shifted to the short wavelength side. Differential scanning calorimetry displayed the glass transition temperature of nanocomposites is much higher than the virgin PMMA. Compared with the original PMMA, with only 1.53 wt% calcium carbonate particulate loading, the PMMA-matrix nanocomposites exhibit higher glass transition temperature. |
關鍵字 | gas-synthesis;glass transition;microstructure;Nanocomposites;Poly(methyl methacrylate) |
語言 | en_US |
ISSN | 0730-6679 |
期刊性質 | 國外 |
收錄於 | SCI |
產學合作 | |
通訊作者 | Lin, C.B |
審稿制度 | 否 |
國別 | USA |
公開徵稿 | |
出版型式 | ,紙本 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/96087 ) |