期刊論文
學年 | 101 |
---|---|
學期 | 2 |
出版(發表)日期 | 2013-05-01 |
作品名稱 | Importance of temperature on the diffusiophoretic behavior of a charge-regulated zwitterionic particle |
作品名稱(其他語言) | |
著者 | Tseng, Shiojenn; Lo, Ting-Wen; Hsu, Chien; Fu, Yu-Kui; Hsu, Jyh-Ping |
單位 | 淡江大學數學學系 |
出版者 | Cambridge: R S C Publications |
著錄名稱、卷期、頁數 | Physical Chemistry Chemical Physics 15(20), pp.7512-7519 |
摘要 | Previous theoretical diffusiophoresis analyses were usually based on a fixed temperature, and its influence on the diffusiophoresis behavior of a particle was seldom discussed. Because both the physicochemical properties of the liquid phase and the charged conditions of a particle can be influenced appreciably by the temperature, so is diffusiophoresis behavior. This effect is taken into account in the present study for the first time, along with the possible presence of multiple ionic species in the liquid phase, a factor of practical significance if reactions occur on the particle surface and/or the solution pH is adjusted. Taking an aqueous dispersion of SiO2 particles as an example, a thorough numerical simulation is conducted to examine the behavior of a charge-regulated, zwitterionic particle subject to an applied salt concentration gradient under various conditions. Considering the potential applications of diffusiophoresis, the results gathered provide necessary information for the design of diffusiophoresis devices, and empirical relationships that correlate the scaled particle mobility with key parameters are developed for that purpose. |
關鍵字 | |
語言 | en_US |
ISSN | 1463-9076 1463-9084 |
期刊性質 | 國外 |
收錄於 | SCI |
產學合作 | |
通訊作者 | |
審稿制度 | |
國別 | GBR |
公開徵稿 | |
出版型式 | 紙本 電子版 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/96062 ) |