期刊論文
學年 | 82 |
---|---|
學期 | 1 |
出版(發表)日期 | 1993-08-01 |
作品名稱 | Magnetic Hyperfine Mössbauer Spectra of Ferrocenyaldimines-FeCl3 Adducts |
作品名稱(其他語言) | |
著者 | 李綺縑; Lee, C. J.; 魏和祥; Wei, Ho-hsiang |
單位 | 淡江大學化學學系 |
出版者 | 臺北市:中國化學學會 |
著錄名稱、卷期、頁數 | Journal of the Chinese Chemical Society=中國化學會會誌 40(4), pp.355-359 |
摘要 | Ferrocenylaldimines (Fc-CH=N-R) were prepared by condensation of Schiff base of formylferrocene with polyacenylamines RNH/sub 2/; R=naphthyl, anthracenyl and pyrenyl groups. This step was followed by oxidation with FeCl/sub 3/ to give [ Fc-CH=NR ] - FeCl/sub 3/ adducts. The electronic state of iron in these adducts was investigated by means of /sup 57/Fe Mossbauer spectra except for [ Fc-CH=N-Pyr ] -FeCl/sub 3/ showed that only a doublet was observed at ambient temperature. As the temperature was decreased below 200K, additional magnetic hyperfine splitting was observed characteristic of ferric oxide. |
關鍵字 | |
語言 | en |
ISSN | 0009-4536 |
期刊性質 | 國內 |
收錄於 | SCI |
產學合作 | |
通訊作者 | |
審稿制度 | 否 |
國別 | TWN |
公開徵稿 | |
出版型式 | ,紙本 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25032 ) |