期刊論文

學年 97
學期 2
出版(發表)日期 2009-05-01
作品名稱 Effect of Electroosmotic Flow on the Electrophoresis of a Membrane-Coated Sphere along the Axis of a Cylindrical Pore
作品名稱(其他語言)
著者 Hsu, Jyh-Ping; Chen, Zheng-Syun; Tseng, Shiojenn
單位 淡江大學數學學系
出版者 Washington, DC: American Chemical Society
著錄名稱、卷期、頁數 The Journal of Physical Chemistry B 113(21), pp.7701–7708
摘要 The electrophoresis of a membrane-coated spherical particle along the axis of a long, charged cylindrical pore was analyzed theoretically under the conditions of low surface potential and weak applied electrical field. The influences of the thickness of the double layer, the pore radius, the nature of the membrane layer, and the charged conditions of the particle and the pore on the electrophoretic behavior of the particle were investigated. The occurrence of the electroosmotic flow and the presence of the membrane layer were found to have a significant influence on the mobility of the particle. For instance, because the direction of electrophoresis does not depend solely on the applied electrical field and the nature of the charge carried by the particle, care must be taken in interpreting electrophoresis data. Furthermore, the magnitude of the electrophoretic mobility of a particle can show a local maximum as the concentration of electrolytes varies, which is of practical significance if electrophoresis is employed, for example, as a separation tool.
關鍵字
語言 en
ISSN 1520-6106; 1520-5207
期刊性質 國外
收錄於 EI SCI
產學合作
通訊作者 Hsu, Jyh-Ping
審稿制度
國別 USA
公開徵稿
出版型式 紙本
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