期刊論文
學年 | 94 |
---|---|
學期 | 2 |
出版(發表)日期 | 2006-06-01 |
作品名稱 | Fitting TGA Data of Oil Sludge Pyrolysis and Oxidation by Applying a Model Free Approximation of the Arrhenius Parameters |
作品名稱(其他語言) | |
著者 | Wu, R. M.; D. J. Lee; C. Y. Chang; J. L. Shie |
單位 | 淡江大學化學工程與材料工程學系 |
出版者 | Amsterdam: Elsevier BV |
著錄名稱、卷期、頁數 | Journal of Analytical and Applied Pyrolysis 76(1-2), pp.132-137 |
摘要 | Interpreting the thermal pyrolysis data from organic substances using thermogravimetric analysis (TGA) requires assuming certain formal kinetic models to be a priori for parametric fitting. The form of the assumed model limits the accuracy of stimulating the pyrolysis data. This work demonstrates the feasibility of modeling the pyrolyzed sample as a continuous mixture, in which an Arrhenius-type kinetics is applied with activation energy, pre-exponential factor, and reaction order as continuous functions of conversion. Such a data fitting scheme is not used to identify the actual chemical kinetics involved, but rather to describe the complex chemical kinetics in a unified, “model free” manner for engineering applications. |
關鍵字 | Thermal pyrolysis; Continuous mixture; Oil sludge; Kinetics |
語言 | en |
ISSN | 0165-2370 |
期刊性質 | 國外 |
收錄於 | SCI EI |
產學合作 | |
通訊作者 | |
審稿制度 | |
國別 | NLD |
公開徵稿 | |
出版型式 | 紙本 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/88212 ) |