期刊論文

標題 Crystal structure of triphenylselenonium chloride dihydrate
學年 64
學期 1
出版(發表)日期 1976/01/01
作品名稱 Crystal structure of triphenylselenonium chloride dihydrate
作品名稱(其他語言)
著者 李榮熹; Lee, Jung-si; Titus, Donald D.
單位 淡江大學化學學系
出版者
著錄名稱、卷期、頁數 Journal of crystal and molecular structure 6(6), pp.279-289
摘要 The structure of triphenylselenonium chloride dihydrate has been determined by single-crystal X-ray diffraction techniques. Crystals of the compound C18H15Se+, Cl−, 2H2O are monoclinic, space groupC2/c, witha = 12.798(3),b = 13.802(1),c = 19.933(34) Å, β = 9.0.0(1) ° andZ = 8. The structure was refined by full-matrix least-squares methods from 1444 diffraotometer intensities to a conventionalR of 0.067 and a weightedR of 0.072. The structure consists of pairs of triphenylselenonium cations which are weakly joined through pairs of bridging chloride ions. The water molecules are clustered in groups of four, separated by the triphenylselenonium chloride dimers. The hydrogen atoms of the water could not be positioned unambiguously, but it appears that hydrogen bonds link the four water molecules and the chloride ions together.
關鍵字
語言 英文(美國)
ISSN 0308-4086
期刊性質 國外
收錄於
產學合作
通訊作者
審稿制度
國別 美國
公開徵稿
出版型式 ,紙本