期刊論文
| 學年 | 92 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2003-08-01 |
| 作品名稱 | Kinetic Study on the Reaction of Yba2cu3oy Powder With Water |
| 作品名稱（其他語言） | |
| 著者 | Yu, F.C.; Lin, C.H.; Wang, C.M.; Kao, H.-C.I. |
| 單位 | 淡江大學化學學系 |
| 出版者 | Singapore: World Scientific Publishing Co. Pte. Ltd. |
| 著錄名稱、卷期、頁數 | International Journal of Modern Physics B 17(18-20), pp.3629-3635 |
| 摘要 | The reaction of superconducting YBa2Cu3Oy powder with water is studied inetically. The initial rate law is found as Ro = k[S]ao [H3O+]bo where [S]o is the initial surface area of the solid, a and b is found to be 0.94 ± 0.02 and 0.318 ± 0.002, respectively. For 100.7 mg powder with a mean radius of 0.0265 mm at pH 7.00 and 298 K, Ro is 2.21 X 10-4 mol．min-1. Using a = 1 and b = 0.3, the rate constant, k, obtained at 283, 298 and 313 K is 0.64, 1.84 and 4.91 X 10-3 mol．min-1．cm-2．M-0.3, respectively. The activation energy is 50.0 Kj．mol-1 and pre-exponential factor is 1.09 X 106 mol．min-1．cm-2．M-0.3, as calculated from the Arrhenius equation. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0217-9792 |
| 期刊性質 | |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | Kao, H.-C.I. |
| 審稿制度 | 否 |
| 國別 | SGP |
| 公開徵稿 | |
| 出版型式 | 紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/61637 ) |