期刊論文
| 學年 | 98 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2009-10-29 |
| 作品名稱 | Structure and magnetic property of μ-alkoxo–μ-6-methoxypurinate double bridged dinuclear copper(II) complex |
| 作品名稱（其他語言） | |
| 著者 | Lai, Tung-Ching; Chen, Wen-hao; Lee, Chin-jhan; Wang, Bo-cheng; Wei, Ho-hsiang |
| 單位 | 淡江大學化學學系 |
| 出版者 | Amsterdam: Elsevier BV |
| 著錄名稱、卷期、頁數 | Journal of Molecular Structure 935(1-3), pp.97-101 |
| 摘要 | A new μ-alkoxo–μ-6-methoxypurinate double bridged dinuclear copper(II) complex [Cu2(L)(μ-6-meo-pur)(dmf)] (1) (μ-6-meo-pur = μ-6-methoxypurinate, H3L = 1,3-bis(3,5-tert-butyl-salicylideneamino)-2-propanol; dmf = N,N-dimethylformamide) has been prepared and structurally characterized. The single crystal X-ray analysis show that the structure of complexes 1 is dimeric with two adjacent copper(II) atoms double bridged by μ-alkoxo–μ-purinato with the Cu···Cu distances and Cu–O(alkoxo)–Cu angles 3.227(3) Å and 110.30(11)°, respectively. Magnetic measurements reveal that 1 is a ferromagnetically coupled with exchange parameter of 2J = 56.2 cm−1. DFT calculation of spin density of HOMO for 1 was presented. |
| 關鍵字 | Copper(II) complexes; Dinuclear copper(II) complexes; Purine metal complexs; Alkoxo–purinato bridges; Crystal structures; Magnetic properties |
| 語言 | en |
| ISSN | 0022-2860 |
| 期刊性質 | 國外 |
| 收錄於 | SCI EI |
| 產學合作 | |
| 通訊作者 | Wang, Bo-cheng; Wei, Ho-hsiang |
| 審稿制度 | |
| 國別 | NLD |
| 公開徵稿 | |
| 出版型式 | 紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/61760 ) |