期刊論文
| 學年 | 65 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 1977-05-01 |
| 作品名稱 | Organonitrogen derivatives of metal carbonyls. 10. Cyclopentadienylmetal dicarbonyl ketoximato derivatives of molybdenum and tungsten |
| 作品名稱（其他語言） | |
| 著者 | Chen, Kan-nan; King, R. B. |
| 單位 | 淡江大學化學學系 |
| 出版者 | American Chemical Society |
| 著錄名稱、卷期、頁數 | Inorganic chemistry 16(5), pp.1164-1167 |
| 摘要 | Compounds of the type RR’CNOM(C0)2CSHS (M = Mo and W; R’ = CH3, R = CH3, CH=CH2, CH=C(CH3)2, and (CHJ2CH=CH2; R + R’ = (CH,),) can be prepared by the following three methods: (1) reaction of RR’C=NOSn(CH3)’ with CSH5M(CO),CL; (2) reaction of RR’C==NOLi with CSH5M(CO),C1; (3) reaction of RR’C=NOH with CSH5M(C0)3CI in the presence of pyridine. Ultraviolet irradiation is necessary for the syntheses of the tungsten compounds but not for their molybdenum analogues. The proton and carbon-1 3 NMR spectra of the ten RR’CNOM(C0)2C5H5 derivatives are described and discussed. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0020-1669 1520-510X |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | 紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/61673 ) |