期刊論文

學年 92
學期 1
出版(發表)日期 2003-12-09
作品名稱 Electrical interaction between two planar, parallel dissimilar surfaces in a general electrolytic solution
作品名稱(其他語言)
著者 Hsu, Jyh-ping; Lin, S. H.; 曾琇瑱; Tseng, Shio-jenn
單位 淡江大學數學學系
出版者 American Chemical Society (ACS)
著錄名稱、卷期、頁數 Langmuir 19(25), pp.10610-10616
摘要 The electrical interaction between two planar, parallel dissimilar surfaces, which may have different charged conditions arising from different ion-adsorption mechanisms, in an arbitrary electrolytic solution is investigated theoretically. The electrical interaction force and the interaction energy between these surfaces are evaluated, and analytical expressions for various charged conditions under the Debye−Huckel condition are derived. In general, assuming constant surface potential and assuming constant surface charge density lead respectively to the lower and the upper bounds in the electrical interaction energy between two surfaces. We show that assuming a linear relation between surface potential and surface charge density under the Debye−Huckel condition, as is often done in the literature, is appropriate for two planar parallel surfaces only but becomes inadequate for other orientations or nonplanar surfaces. The present approach does not have this limitation.
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語言 en
ISSN 0743-7463
期刊性質 國內
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國別 TWN
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出版型式 ,電子版
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