期刊論文
| 學年 | 93 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2005-04-28 |
| 作品名稱 | Derivation of analytical expressions for the electrical potential distribution in lipid structures |
| 作品名稱（其他語言） | |
| 著者 | 曾琇瑱; Tseng, Shio-jenn; Hsu, Jyh-ping; Jiang, J. M. |
| 單位 | 淡江大學數學學系 |
| 出版者 | American Chemical Society (ACS) |
| 著錄名稱、卷期、頁數 | Journal of Physical Chemistry B 109(16), pp.8180-8184 |
| 摘要 | The electrical potential inside a lipid structure, which is described by a modified Poisson−Boltzmann equation in the literature (Borukhov et al. Electrochim. Acta 2000, 46, 221), is solved, taking into account the effects of ionic sizes. Here, a micelle comprises an ionic surfactant layer and an aqueous core; the dissociation of the former yields a charged surface. The governing equation, which was solved numerically in a previous study for spherical geometry (Hsu et al. J. Phys. Chem. B 2003, 107, 14429), is solved analytically in this study for planar, cylindrical, and spherical geometries. The analytical results obtained are readily applicable for the evaluation of the spatial distributions of counterions inside a lipid structure. We show that if the linear size of a reverse micelle is fixed, the degree of dissociation of the surfactant layer follows the order planar > cylindrical > spherical. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 1520-6106 |
| 期刊性質 | 國內 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/41334 ) |