期刊論文
| 學年 | 91 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2002-08-01 |
| 作品名稱 | A two-dimensional CuIIGdIII compound self-assembled by H-bonding and intermolecular weak coordinate bonding between the dinuclear cores: structure and magnetic properties |
| 作品名稱（其他語言） | |
| 著者 | 魏和祥; Wei, Ho-hsiang; Mohanta, Sasankasekhar; Lin, Hsin-huang; Lee, Chin-jhan |
| 單位 | 淡江大學化學學系 |
| 出版者 | Elsevier |
| 著錄名稱、卷期、頁數 | Inorganic Chemistry Communications 5(8), pp.585-588 |
| 摘要 | A heteronuclear CuIIGdIII complex [CuIILGdIII(NO3)3] with the hexadentate Shiff-base compartmental ligand N,N′-ethylenebis(3-ethoxysalicylaldiimine) (H2L) has been synthesized and structurally characterized. The intermolecular semicoordination of nitrate oxygen to copper(II) results a one-dimensional zigzag chain, which are linked by H-bonding to form a two-dimensional sheet. Magnetic studies reveal ferromagnetic interaction within the dinuclear core and antiferromagnetic interaction propagated through the extended network (Full-size image (<1 K), where H=−2JSCu·SGd+β(gCu·SCu+gGd·SGd)H−zJ′〈S4Z〉S4Z). |
| 關鍵字 | Two-dimensional; H-bonding; Magnetic properties; Gadolinium |
| 語言 | en |
| ISSN | 1387-7003 |
| 期刊性質 | 國內 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25456 ) |