期刊論文
學年 | 80 |
---|---|
學期 | 2 |
出版(發表)日期 | 1992-04-01 |
作品名稱 | Mössbauer and magnetic studies on the spin states of mono- and binuclear iron(III) complexes with quinquedentate ligand methyl-substituted pyridine and bridged by pyrazine or bis(pyridine) compounds |
作品名稱(其他語言) | 雙鐵(III)-仆咻-雙銅(II)錯合物之梅氏及磁性研究 |
著者 | Wei, Ho-hsiang; Sheu, Jinn-fu |
單位 | 淡江大學化學學系 |
出版者 | Dordrecht: Springer Netherlands |
著錄名稱、卷期、頁數 | Hyperfine interactions 68(1-4), pp.257-260 |
摘要 | Mono- and binuclear iron(III) complexes with the general formula [FeXL] and [LFe-Y-FeL](BPh4)2 have been prepared and their spin states of the iron atom in the complexes has been investigated by means of the temperature-dependent Mössbauer spectroscopy and magnetic measurements, where X is a methyl-substituted pyridine, L denotes a quinquedentate Schiff-base derived from salicylaldehyde with N-(2-aminoethyl)-1,3-propanediamine and Y denotes bridged ligands such as pyrazine(pyr), 4,4′-pyridine(bpy), 4,4′-vinylenepyridine(vipy). On the basis of the Mössbauer and magnetic data, it was concluded that the spintransition characteristics depends on the methyl substituent of pyridine and the bridged ligand. |
關鍵字 | |
語言 | en |
ISSN | 0304-3843 1572-9540 |
期刊性質 | 國外 |
收錄於 | |
產學合作 | |
通訊作者 | |
審稿制度 | |
國別 | NLD |
公開徵稿 | |
出版型式 | 紙本 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25064 ) |