期刊論文
| 學年 | 83 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 1994-12-01 |
| 作品名稱 | Mössbauer and magnetic studies on the spin states of diiron(III)-porphyrin dicopper(II) complexes |
| 作品名稱（其他語言） | |
| 著者 | Huang, S. F.; Wei, Ho-hsiang |
| 單位 | 淡江大學化學學系 |
| 出版者 | Dordrecht: Springer Netherlands |
| 著錄名稱、卷期、頁數 | Hyperfine interactions 91(1), pp.809-814 |
| 摘要 | Several biological model complexes of cytochrome c oxidase analogues, such as X2(TPP)2Fe2(Apen)Cu2Cl4, where TPP=5, 10, 15, 20-tetraphenylporphine, Apen=bis(acetylpyrazine)-ethylenediimine, X=Cl−, N 3 −, Im, 1-Me-Im, 2-Me-Im, 4-Me-Im and OCH 3 −, were prepared. The electronic spin states of these complexes in solid state were studied by means of Mössbauer and EPR spectroscopies and magnetic susceptibility measurements. The iron(III) atom of these complexes is present in different spin states, depending upon the nature of the axial ligand X of Fe(III)-porphyrin; the N 3 −, Cl−, OCH 3 −, 2-Me-Im axial groups lead to complexes in a pure high-spin state independent of temperature. In contrast, the imidazole axial groups (e.g. Im, 4-Me-Im) behave differently and all show a temperature dependence of the6A1 ↔2T2 spin transition. The magnetic exchange behavior between Fe and Cu atoms in the present complexes is also discussed. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0304-3843 1572-9540 |
| 期刊性質 | 國外 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | |
| 國別 | NLD |
| 公開徵稿 | |
| 出版型式 | 紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25063 ) |