期刊論文
| 學年 | 97 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2009-02-01 |
| 作品名稱 | Electrochemistry of Nitrated Fullerene Derivatives |
| 作品名稱（其他語言） | |
| 著者 | 王文竹; Wang, Wen-jwu; Chiu, H. S.; Chang, C. S.; Chiang, Long Y. |
| 單位 | 淡江大學化學學系 |
| 出版者 | Elsevier |
| 著錄名稱、卷期、頁數 | Diamond and Related Materials 18(2-3), pp.469-471 |
| 摘要 | Hexanitro[60]-fullerene was synthesized. Hexahydroxy[60]-fullerene was obtained by hydrolysis of the resulting hexanitro[60]-fullerene in situ. The electrochemical properties have been investigated by using cyclic voltammetry and controlled potential electrolysis technique. Two reduction peaks of C60(OH)6 with quasi-reversibility in DMF solution were observed. No electrochemical response was observed for the C60(OH)12 compound in a variety of solvent. An electrode following chemical reaction occurred for C60(NO2)6 after the first reduction at − 0.96 V. The trace amount residue of C60(NO2)6 shows quasi-reversible redox behavior. The results from the controlled potential electrolysis show that the C60(NO2)6 has six sequential electron transfer at − 0.96 V (vs. Fc/Fc+) to produce free C60 and NO2− anion. |
| 關鍵字 | Electrochemistry;C60 derivatives;Nitrated fullerenes;Hydroxylated fullerenes |
| 語言 | en |
| ISSN | 0925-9635 |
| 期刊性質 | 國內 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/50367 ) |