期刊論文
| 學年 | 91 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2002-10-10 |
| 作品名稱 | NMR spectroscopic studies of dimethyldiethoxy silane hydrolysis and polysiloxane conversion |
| 作品名稱（其他語言） | |
| 著者 | Tsai, Ming-fu; Lee, Yu-der; Chen, Kan-nan |
| 單位 | 淡江大學化學學系 |
| 出版者 | John Wiley & Sons |
| 著錄名稱、卷期、頁數 | Journal of Applied Polymer Science 86(2), pp.468-477 |
| 摘要 | The hydrolysis rate of alkoxy silane (dimethyldiethoxy silane, DMDES, etc.) is a linear relationship vs. the reaction time under the moisture flux control. The hydrolysis process results in formation of the linear polysiloxane products by a subsequent condensation reaction. An amidized alkoxy silane (3-(2-aminoethyl)aminopropylmethyldimethoxy silane, KLM-602 or -aminopropyl- triethoxy silane, -APS) serves as an internal standard of DMDES hydrolysis kinetics measurements. The hydrolysis kinetics of DMDES with the amidized alkoxy silane and the subsequent linear polysiloxanes conversion have been evaluated and characterized by 29Si- and 13C-NMR NMR spectroscopic measurements. |
| 關鍵字 | |
| 語言 | en_US |
| ISSN | 0021-8995 |
| 期刊性質 | 國外 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | ,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/19536 ) |