期刊論文
| 學年 | 92 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2003-12-20 |
| 作品名稱 | Polymer hybrids from self-emulsified PU anionomer and water-reducible acrylate copolymer via a postcuring reaction |
| 作品名稱（其他語言） | |
| 著者 | Lai, Jian-zei; Ling, Hao-Jan; Chen, Guan-nan; Yeh, Jen-taut; Chen, Kan-nan |
| 單位 | 淡江大學化學學系 |
| 出版者 | John Wiley & Sons |
| 著錄名稱、卷期、頁數 | Journal of Applied Polymer Science 90(13), pp.3578-3587 |
| 摘要 | Water-reducible acrylate copolymer is obtained from a free-radical copolymerization of n-butyl acrylate, acrylic acid, and methacrylic acid. Self-emulsified aqueous-based polyurethane (PU) anionomer is prepared by the conventional method. The latent curing agents (di- and triaziridinyl compounds, HDDA-AZ and TMPTA-AZ) are synthesized from the reaction of aziridine with hexandiol diacrylate and trimethylolpropane triacrylate, respectively. These two polymers and the latent curing agent are miscible in each other and become a single component and self-curable polymer dispersion. The carboxyl ions of polymers not only stabilize the aqueous polymer dispersions but also serve the curing site toward latent curing agent in the drying process. These two polymers blend with a curing agent, which results in new polymer hybrid formation. These polymer hybrids have the improvements on performance properties and the cost/performance benefits. |
| 關鍵字 | |
| 語言 | en_US |
| ISSN | 0021-8995 |
| 期刊性質 | 國外 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/19526 ) |