期刊論文
| 學年 | 85 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 1997-07-01 |
| 作品名稱 | Convenient post-curing reactions for aqueous-based polyurethane anionomers |
| 作品名稱（其他語言） | |
| 著者 | Chen, Guan-nan; Liu, Po-hong; Chen, Maw-shuh; Chen, Kan-nan |
| 單位 | 淡江大學化學學系 |
| 出版者 | Springer |
| 著錄名稱、卷期、頁數 | Journal of Polymer Research 4(3), pp.165-175 |
| 摘要 | Anionic aqueous-based polyurethane (PU) dispersions were prepared by introducing carboxylic groups into a conventional PU backbone, followed by a water dispersion process. The resulting carboxylic groups containing aqueous-based PUs were amino-terminated anionomers. Two model reactions between an amino and a carboxylic group containing compounds with an epoxide and an aziridinyl compound, respectively were carried out at ambient temperature. Di-functional epoxide and aziridinyl compound were employed as the convenient single post-curing and dual-curing agents for these prepared PU dispersions. Di-aziridinyl compound was stable in aqueous PU dispersions as a latent curing agent when the pH value of the system was 8.0 or above. The curing behaviors of each PU curing system were monitored by measurements of the gel content, average particle size, zeta potential, and fluorescence spectra. The mechanical and thermal properties of these post-cured PUs were evaluated. |
| 關鍵字 | Aqueous-based PU anionomers;Aziridinyl;Epoxide;Ambient temperature curing |
| 語言 | en |
| ISSN | 1022-9760 |
| 期刊性質 | 國內 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/19518 ) |