期刊論文
| 學年 | 83 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 1995-03-15 |
| 作品名稱 | Electrochemiacl doping of tetraethylammonium on C60 film |
| 作品名稱（其他語言） | 以電化學方法植入Tetraethylammonium在C60薄膜中 |
| 著者 | 王文竹; Wang, Wen-jwu; Chiu, Hau-shy; 余良杰; Yu, Liang-jye; 王伯昌; Wang, Bo-cheng |
| 單位 | 淡江大學化學學系 |
| 出版者 | Elsevier |
| 著錄名稱、卷期、頁數 | Synthetic metals 70(1-3), pp.1439-1442 |
| 摘要 | The electrochemical behavior of C60 films, which was prepared on electrode by solution casting method, during redox processes in acetonitrile solution containing tetraethylammonium perchlorate as supporting electrolyte was examined by means of cyclic voltammetry (CV) and electrochemical quartz crystal microbalance (EQCM) technique. In the CV behavior, there are four reductive waves at R1=-1.17 V, R2=-1.25 V, R3=-1.40 V and R4=-1.55 V vsFc/Fc+ which are corresponding to C60(TEA+)/C60-(TEA+), C60/C60, C60 (TEA+)/C60−2 reactions, respectively. There are four reoxidative waves at 04=-1.29 V, 03=-1.06 V, 02=-0.76 V and 01=-0.55 V vs Fc/Fc+ which are corresponding to C60−2 deposition on film, C60-/C60, and C60−2(TEA+)2/C60-(TEA+)/C60(TEA-), respectively. The dissolution/ depositive of C60−n(n=1,2) and doping / dedoping of TEA+ on C60 films at different potential are investigated and approved by EQCM studied. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0379-6779 |
| 期刊性質 | 國內 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24951 ) |