關鍵字查詢 | 類別:期刊論文 | | 關鍵字:Synthesis and stability study of isocyano aryl boronate esters and their synthetic applications

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序號 學年期 教師動態
1 104/2 化學系 謝忠宏 助理教授 期刊論文 發佈 Synthesis and stability study of isocyano aryl boronate esters and their synthetic applications , [104-2] :Synthesis and stability study of isocyano aryl boronate esters and their synthetic applications期刊論文Synthesis and stability study of isocyano aryl boronate esters and their synthetic applicationsFang, Hao-Ping; Fu, Chia-Chieh; Tai, Chin-Kuen; Chang, Ken-Hao; Yang, Ru-Han; Wu, Meng-Ju; Chen, Hsien-Chi; Li, Chia-Jung; Huang, Shi-Qing; Lien, Wan-Hsiang;RSC Advances 6(36), p.30362-30371A facile synthesis of isocyano arylboronate esters is reported. Although tri-coordinate boron functional groups are commonly recognized as vulnerable to nucleophilic attack, the newly reported tri-coordinate isocyano arylboronate esters were found to be stable, albeit owing to the presence of an isocyano group. Theoretical calculations, using the DFT/B3LYP/6-31G(d,p) method, revealed that the electron delocalization between the aryl group and the boron atom might contribute to this stability. UV-vis spectroscopic investigations on 2-(4-isocyanophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (2a) were in agree
2 104/2 化學系 王伯昌 教授 期刊論文 發佈 Synthesis and stability study of isocyano aryl boronate esters and their synthetic applications , [104-2] :Synthesis and stability study of isocyano aryl boronate esters and their synthetic applications期刊論文Synthesis and stability study of isocyano aryl boronate esters and their synthetic applicationsHao-Ping Fang; Chia-Chieh Fu; Chin-Kuen Tai; Ken-Hao Chang; Ru-Han Yang; Meng-Ju Wu; Hsien-Chi Chen; Chia-Jung Li; Shi-Qing Huang; Wan-Hsiang Lien; Chih-Hsin Chen; Chung-Hung Hsieh; Bo-Cheng Wang; Siu-Fung Cheung; Po-Shen Panboronate ester;isocyanide;multicomponent reactionRSC Advances 6, pp.30362-30371A facile synthesis of isocyano arylboronate esters is reported. Although tri-coordinate boron functional groups are commonly recognized as vulnerable to nucleophilic attack, the newly reported tri-coordinate isocyano arylboronate esters were found to be stable, albeit owing to the presence of an isocyano group. Theoretical calculations, using the DFT/B3LYP/6-31G(d,p) method, revealed that the electron delocalization between the aryl group and the boron atom might contribute to this stability. UV-v
3 104/2 化學系 潘伯申 副教授 期刊論文 發佈 Synthesis and stability study of isocyano aryl boronate esters and their synthetic applications , [104-2] :Synthesis and stability study of isocyano aryl boronate esters and their synthetic applications期刊論文Synthesis and stability study of isocyano aryl boronate esters and their synthetic applicationsHao-Ping Fang; Chia-Chieh Fu; Chin-Kuen Tai; Ken-Hao Chang; Ru-Han Yang; Meng-Ju Wu; Hsien-Chi Chen; Chia-Jung Li; Shi-Qing Huang; Wan-Hsiang Lien; Chih-Hsin Chen; Chung-Hung Hsieh; Bo-Cheng Wang; Siu-Fung Cheung; Po-Shen Panboronate ester;isocyanide;multicomponent reactionRSC Advances 6, pp.30362-30371A facile synthesis of isocyano arylboronate esters is reported. Although tri-coordinate boron functional groups are commonly recognized as vulnerable to nucleophilic attack, the newly reported tri-coordinate isocyano arylboronate esters were found to be stable, albeit owing to the presence of an isocyano group. Theoretical calculations, using the DFT/B3LYP/6-31G(d,p) method, revealed that the electron delocalization between the aryl group and the boron atom might contribute to this stability. UV-v
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