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化材系 陳幹男 教授於
期刊論文
發佈
A New Self-Polymerization of Acrylic Acid with a Mono-aziridine Containing Compound
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：A New Self-Polymerization of Acrylic Acid with a Mono-aziridine Containing Compound期刊論文A New Self-Polymerization of Acrylic Acid with a Mono-aziridine Containing CompoundChen, Po-Cheng; Wang, Shih-Chieh; Hwang, Jing-Zhong Yeh, Jen-Taut; Huang, Chi-Yuan; Chen, Kan-Nan淡江大學化學學系臺北市：中國化學學會Journal of the Chinese Chemical Society=中國化學會會誌 57(4)pt.B, pp.901-908A new self-polymerization took place between acrylic acid (AA) and a mono-aziridine containing compound, e.g. methyl 3-(aziridin-1-yl) propanoate (MAP) upon mixing that resulted in formation of a linear polyethyleneimine (PEI) with amino-ester bonds. This self-polymerization has a key reaction of ring opening reaction occurred between carboxylic acid and aziridine that led to an amino-ester bond formation. The model reactions of trimethylacetic acid (TMAA) with MAP and then with ethyl acrylate (EA) were designed to demonstrat the self-polymerization mechanism. The model reaction product at each stage related to that of polymerization was
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