教師資料查詢 | 類別: 期刊論文 | 教師: 陳登豪 CHEN, TENG-HAO (瀏覽個人網頁)

標題:A Zirconium Macrocyclic Metal–Organic Framework with Predesigned Shape-Persistent Apertures
學年105
學期1
出版(發表)日期2017/01/05
作品名稱A Zirconium Macrocyclic Metal–Organic Framework with Predesigned Shape-Persistent Apertures
作品名稱(其他語言)
著者Teng-Hao Chen; Ilya Popov; Ognjen S. Miljanic
單位
出版者
著錄名稱、卷期、頁數Chemistry - A European Journal 23(2), pp.286-290
摘要A microporous metal–organic framework (MOF) was synthesized from [Zr6O4(OH)4(C6H5COO)12] clusters and a triacid ligand based on a shape-persistent arylene ethynylene macrocycle. This framework, dubbed Zr-MCMOF, is held together by metal–ligand coordination and multiple weak interactions: hydrogen bonding, [π⋅⋅⋅π] stacking, and [C−H⋅⋅⋅π] interactions. The rigid ligand has a 9 Å-wide central void, which serves as a predesigned aperture for the 1D channels; all of the porosity of Zr-MCMOF comes from the ligand. The resulting framework possesses high hydrolytic and thermal stability and a flexible structure unique among Zr-based MOFs.
關鍵字1D channels;macrocycles;metal–organic frameworks;shape persistency;zirconium
語言英文
ISSN1521-3765
期刊性質國外
收錄於SCI;
產學合作國外;
通訊作者Teng-Hao Chen; Ognjen S. Miljanic
審稿制度
國別德國
公開徵稿
出版型式,電子版
相關連結
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