Photofunctional Platinum Complexes Featuring N-heterocyclic Carbene-Based Pincer Ligands
學年 103
學期 2
出版(發表)日期 2015-03-01
作品名稱 Photofunctional Platinum Complexes Featuring N-heterocyclic Carbene-Based Pincer Ligands
作品名稱(其他語言)
著者 Lin, Wan-Jung; Abbas Raja Naziruddin; Chen, Yu-Hsuan; Sun, Bian-Jian; Chang, Hsiu Hwa; Wang, Wen-Jwu; Hwang, Wen-Shu
單位 淡江大學化學學系
出版者 Weinheim: Wiley - V C H Verlag GmbH & Co. KGaA
著錄名稱、卷期、頁數 Chemistry – An Asian Journal 10(3), pp.728-739
摘要 Photoactive platinum complexes of stoichiometry [Pt(RCCCR)L]0/+ (R=Me, nBu and L=[BOND]CN, [BOND]C≡CPh, [BOND]N≡CCH3, [BOND]Py, [BOND]CO) featuring pincer-type bis N-heterocyclic carbene (NHC) ligands (RCCCR) were synthesized. Organometallic syntheses of these complexes are facile and achievable through standard laboratory procedures. Control of intermolecular Pt⋅⋅⋅Pt interaction, π–π stacking, and emission tuning is achieved through suitable choice of the NHC-wingtip substituent (R) and the auxiliary ligand (L). Exposure to specific volatile organic compounds (VOCs) or mechanical grinding triggers changes in emission colors, which render these complexes photofunctional. Solid-state structures and photoluminescence results are described herein.
關鍵字
語言 en_US
ISSN 1861-471X
期刊性質 國外
收錄於 SCI
產學合作
通訊作者 Hwang, Wen-Shu
審稿制度
國別 DEU
公開徵稿
出版型式 ,電子版
相關連結

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/101009 )

機構典藏連結