Photofunctional Platinum Complexes Featuring N-heterocyclic Carbene-Based Pincer Ligands | |
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學年 | 103 |
學期 | 2 |
出版(發表)日期 | 2015-03-01 |
作品名稱 | Photofunctional Platinum Complexes Featuring N-heterocyclic Carbene-Based Pincer Ligands |
作品名稱(其他語言) | |
著者 | Lin, Wan-Jung; Abbas Raja Naziruddin; Chen, Yu-Hsuan; Sun, Bian-Jian; Chang, Hsiu Hwa; Wang, Wen-Jwu; Hwang, Wen-Shu |
單位 | 淡江大學化學學系 |
出版者 | Weinheim: Wiley - V C H Verlag GmbH & Co. KGaA |
著錄名稱、卷期、頁數 | Chemistry – An Asian Journal 10(3), pp.728-739 |
摘要 | Photoactive platinum complexes of stoichiometry [Pt(RCCCR)L]0/+ (R=Me, nBu and L=[BOND]CN, [BOND]C≡CPh, [BOND]N≡CCH3, [BOND]Py, [BOND]CO) featuring pincer-type bis N-heterocyclic carbene (NHC) ligands (RCCCR) were synthesized. Organometallic syntheses of these complexes are facile and achievable through standard laboratory procedures. Control of intermolecular Pt⋅⋅⋅Pt interaction, π–π stacking, and emission tuning is achieved through suitable choice of the NHC-wingtip substituent (R) and the auxiliary ligand (L). Exposure to specific volatile organic compounds (VOCs) or mechanical grinding triggers changes in emission colors, which render these complexes photofunctional. Solid-state structures and photoluminescence results are described herein. |
關鍵字 | |
語言 | en_US |
ISSN | 1861-471X |
期刊性質 | 國外 |
收錄於 | SCI |
產學合作 | |
通訊作者 | Hwang, Wen-Shu |
審稿制度 | 否 |
國別 | DEU |
公開徵稿 | |
出版型式 | ,電子版 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/101009 ) |