教師資料查詢 | 類別: 期刊論文 | 教師: 魏和祥 WEI, HO-HSIANG (瀏覽個人網頁)

標題:Mössbauer and Electrochemical Studies of Bridged Biferrocenes and Biferrocenylenes
學年72
學期2
出版(發表)日期1984/03/01
作品名稱Mössbauer and Electrochemical Studies of Bridged Biferrocenes and Biferrocenylenes
作品名稱(其他語言)
著者魏和祥; Wei, Ho-hsiang; 張信貞; Chang, S. J.
單位淡江大學化學學系
出版者臺北市中國化學學會
著錄名稱、卷期、頁數中國化學會會誌=Journal of the Chinese Chemical Society 31(1)頁9-14
摘要A series of neutral and oxidized π-bridged biferrocenes (Fc-x-Fc) and biferrocenylenes (FC(-x-)2Fc) (x=-CH=CH-, -CH3C=CCH3-) were prepared and their physical properties have been studied by means of Mossbauuer and cyclic voltammetry. The electrode reaction of these bridged ferrocene derivatives appears to involve a consecutive two-step oxidation process. The results also show that the voltage difference between the first and second oxidaton potentials of the bridged biferrocenes was found to be largely exceeded that founded for the corresponding the bridged biferrocenylenes. The Mossbauer date show that the oxidation of doubly bridged Fc(-x-)2Fc with iodine, DDQ, and TCNQ given the corresponding deoxidized salts only and stable mixed-valence compounds were found.
關鍵字
語言英文
ISSN0009-4536
期刊性質國內
收錄於SCI;
產學合作
通訊作者
審稿制度
國別中華民國
公開徵稿
出版型式,紙本
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