教師資料查詢 | 類別: 期刊論文 | 教師: 王文竹 WANG, WEN-JWU (瀏覽個人網頁)

標題:Synthesis and characterization of bridged bimetallic complexes(I) copper(II) complesxes with conjugated diimine ligands
學年74
學期1
出版(發表)日期1985/12/01
作品名稱Synthesis and characterization of bridged bimetallic complexes(I) copper(II) complesxes with conjugated diimine ligands
作品名稱(其他語言)
著者王文竹; Wang, Wen-jwu; Ho, C. T.
單位淡江大學化學學系
出版者臺北市中國化學學會
著錄名稱、卷期、頁數中國化學會會誌=Journal of the Chinese Chemical Society 32(4)頁431-438
摘要A series of binucleating ligands with fully conjugated .pi.-systems have been synthesized. Homobinuclear copper(II) complexes of the form [(Cu(dien)ClO/sub 4/)/sub 2/L]-(ClO/sub 4/)/sub 2/, where dien is diethylenetriamine and L is binucleating ligand, were prepared. Mononuclear complexes, with structure similar to that of the preceeding compounds, [Cu(dien)L'(ClO/sub 4/)](ClO/sub 4/) were synthesized as reference compounds. The infrared spectra, electronic spectra and magnetic properties were studied. The inductive effect, steric effect and the effect of the length of the conjugated .pi.-system on the magnetic exchange interaction between the two copper ions are discussed. The electrochemical properties of these complexes were investigated by cyclic voltammetry. The copper ions showed the cooperative phenomena and a quasi-reversible sequential transfer of two electrons at the same potential.
關鍵字Binuclear copper(II) complexes;magnetic;electrochemical properties;magnetic exchange interaction;diimine ligand.
語言英文
ISSN0009-4536
期刊性質國內
收錄於
產學合作
通訊作者
審稿制度
國別中華民國
公開徵稿
出版型式紙本
相關連結
Google+ 推薦功能,讓全世界都能看到您的推薦!