標題:A new UV-curable PU resin obtained through a nonisocyanate process and used as a hydrophilic textile treatment |
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學年 | 100 |
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學期 | 2 |
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出版(發表)日期 | 2012/07/01 |
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作品名稱 | A new UV-curable PU resin obtained through a nonisocyanate process and used as a hydrophilic textile treatment |
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作品名稱(其他語言) | |
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著者 | Hwang, Jing-Zhong; Wang, Shih-Chieh; Chen, Po-Chen; Huang, Chi-Yuan; Yeh, Jen-Taut; Chen, Kan-Nan |
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單位 | 淡江大學化學學系;淡江大學化學工程與材料工程學系 |
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出版者 | Dordrecht: Springer Netherlands |
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著錄名稱、卷期、頁數 | Journal of Polymer Research 19(8), 9900(10pages) |
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摘要 | A new UV-curable hydrophilic PU resin was obtained through a green, nonisocyanate, three-reaction process: (1) a bis(cyclic carbonate) (BCC) compound is prepared by inserting carbon dioxide into an epoxy resin (DGEBA) at atmospheric pressure; (2) an amino-terminated hydrophilic PU (NH2-PU) oligomer is obtained through the ring-opening polymerization of BCC utilizing a difunctional amino hydrophilic (polyether) compound such as Jeffamine D-2000; (3) the UV-curable acrylate-PU (UV-PU) prepolymer is obtained as an adduct from the Michael addition of NH2-PU to a diacrylate-terminated compound, 3-acryloyloxy-2-hydroxypropyl methacrylate (AHM). A polyester (PET) textile was treated with this hydrophilic UV-PU prepolymer and then cured by irradiation with UV light. The UV-PU resin was found to crosslink and anchor to the textile fibers after UV irradiation, resulting in a long-lasting hydrophilic surface for the treated textile. The performance properties of the new PU resin on the treated textile were investigated. |
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關鍵字 | Nonisocyanate process; Cyclic carbonate; Hydrophilic; PU; UV curing |
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語言 | 英文 |
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ISSN | 1022-9760; 1572-8935 |
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期刊性質 | 國外 |
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收錄於 | SCI |
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產學合作 | |
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通訊作者 | |
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審稿制度 | 是 |
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國別 | 荷蘭 |
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公開徵稿 | |
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出版型式 | 紙本 |
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相關連結 | |
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