教師資料查詢 | 類別: 期刊論文 | 教師: 林正嵐 Cheng-lan Lin (瀏覽個人網頁)

標題:Micropipet Delivery−Substrate Collection Mode of Scanning Electrochemical Microscopy for the Imaging of Electrochemical Reactions and the Screening of Methanol Oxidation Electrocatalysts
學年98
學期1
出版(發表)日期2009/10/01
作品名稱Micropipet Delivery−Substrate Collection Mode of Scanning Electrochemical Microscopy for the Imaging of Electrochemical Reactions and the Screening of Methanol Oxidation Electrocatalysts
作品名稱(其他語言)
著者Lin, Cheng-lan; Rodrguez-Lpez, Joaqun; Bard, Allen J.
單位淡江大學化學工程與材料工程學系
出版者American Chemical Society
著錄名稱、卷期、頁數Analytical Chemistry 81(21), pp.8868-8877
摘要The micropipet delivery−substrate collection (MD−SC) mode of scanning electrochemical microscopy (SECM) is demonstrated. This new mode is intended for the study and imaging of electrochemical as well as electrocatalytic reactions of neutral species that cannot be generated electrochemically. The spontaneous transfer of the analyte from an organic solvent across an interface between two immiscible electrolyte solutions (ITIES) and its diffusion into the aqueous solution served as the mechanism to deliver it to the substrate, where the corresponding electrochemical or electrocatalytic reaction is carried out. High-resolution SECM images of ferrocenemethanol (FcMeOH) oxidation, benzoquinone (BQ) reduction, and the formic acid oxidation reaction (FAOR) at a Pt microelectrode substrate were successfully acquired. Furthermore, this new mode was used for the screening of electrocatalyst arrays for the methanol oxidation reaction (MOR), with the optimization of an efficient candidate, Pt80Ce20. Digital simulations produced quantitative information about the expected current response at the substrate in the proposed MD−SC mode of SECM.
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語言英文
ISSN0003-2700
期刊性質國外
收錄於SCI;EI
產學合作
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