教師資料查詢 | 類別: 期刊論文 | 教師: 魏和祥 WEI, HO-HSIANG (瀏覽個人網頁)

標題:Ferromagnetic Exchange in Two Dicopper(II) Complexes Using a μ-Alkoxo-μ-7-azaindolate Bridge
學年92
學期2
出版(發表)日期2004/05/03
作品名稱Ferromagnetic Exchange in Two Dicopper(II) Complexes Using a μ-Alkoxo-μ-7-azaindolate Bridge
作品名稱(其他語言)
著者Chou, Yi-chian; Huang, Shu-fei; Koner, Rajesh; Lee, Gene-hsiang ; Wang, Yu; Mohanta, Sasankasekhar; 魏和祥; Wei, Ho-hsiang
單位淡江大學化學學系
出版者American Chemical Society (ACS)
著錄名稱、卷期、頁數Inorganic chemistry 43(9), pp.2759-2761
摘要Syntheses, structures, and magnetic properties of two heterobridged μ-alkoxo-μ-7-azaindolate dicopper(II) complexes, [CuII2(L−F)(μ-C7H5N2)] (1) and [CuII2(L−H)(μ-C7H5N2)]·CH3OH (2) (H3L−F = 1,3-bis(3-fluorosalicylideneamino)-2-propanol; H3L−H = 1,3-bis(salicylideneamino)-2-propanol) have been reported. Aside from being a new type of heterobridged complex, 1 and 2 exhibit ferromagnetic interaction (2J = 52 cm-1 for 1 and 33.4 cm-1 for 2) despite orbital complementarity (7-azaindolate HOMO is antisymmetric).
關鍵字
語言英文
ISSN0020-1669
期刊性質國內
收錄於
產學合作
通訊作者
審稿制度
國別中華民國
公開徵稿
出版型式,電子版
相關連結
Google+ 推薦功能,讓全世界都能看到您的推薦!