教師資料查詢 | 類別: 期刊論文 | 教師: 魏和祥 WEI, HO-HSIANG (瀏覽個人網頁)

標題:Ferromagnetic coupling in a novel dicyanamide-bridged dinuclear gadolinium(III) complex [Gd2(dca)4(OH)2 (NITpPy)4] (NITpPy = 4-pyridyl-nitronyl nitroxide radical)
學年94
學期1
出版(發表)日期2005/12/01
作品名稱Ferromagnetic coupling in a novel dicyanamide-bridged dinuclear gadolinium(III) complex [Gd2(dca)4(OH)2 (NITpPy)4] (NITpPy = 4-pyridyl-nitronyl nitroxide radical)
作品名稱(其他語言)
著者魏和祥; Wei, Ho-hsiang; Hsu, Chin-feng; Lin, Shin-huang
單位淡江大學化學學系
出版者Elsevier
著錄名稱、卷期、頁數Inorganic Chemistry Communications 8(12), pp. 1128-1132
摘要The novel six-coordinated gadolinium(III) complex of formula [Gd2(dca)4(OH)2(NITpPy)4] (1) (dca = dicyanamide, NITpPy = 4-pyridyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-oxy-3-oxide) has been prepared and characterized by X-ray crystallography. Compound 1 is a dimer structure made up of double μ1,5-dca-bridged gadolinium(III) ions and one terminal dca ligand; variable-temperature magnetic susceptibility measurements reveal the occurrence of a significant ferromagnetic interaction directly spin polarization through the NITpPy–Gd(III)–NITpPy pathway with J = 11.56 cm−1.
關鍵字
語言英文
ISSN1387-7003
期刊性質國內
收錄於
產學合作
通訊作者
審稿制度
國別中華民國
公開徵稿
出版型式,電子版
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