教師資料查詢 | 類別: 期刊論文 | 教師: 王文竹 WANG, WEN-JWU (瀏覽個人網頁)

標題:Electrochemistry of Nitrated Fullerene Derivatives
學年97
學期2
出版(發表)日期2009/02/01
作品名稱Electrochemistry of Nitrated Fullerene Derivatives
作品名稱(其他語言)
著者王文竹; Wang, Wen-jwu; Chiu, H. S.; Chang, C. S.; Chiang, Long Y.
單位淡江大學化學學系
出版者Elsevier
著錄名稱、卷期、頁數Diamond and Related Materials 18(2-3), pp.469-471
摘要Hexanitro[60]-fullerene was synthesized. Hexahydroxy[60]-fullerene was obtained by hydrolysis of the resulting hexanitro[60]-fullerene in situ. The electrochemical properties have been investigated by using cyclic voltammetry and controlled potential electrolysis technique. Two reduction peaks of C60(OH)6 with quasi-reversibility in DMF solution were observed. No electrochemical response was observed for the C60(OH)12 compound in a variety of solvent. An electrode following chemical reaction occurred for C60(NO2)6 after the first reduction at − 0.96 V. The trace amount residue of C60(NO2)6 shows quasi-reversible redox behavior. The results from the controlled potential electrolysis show that the C60(NO2)6 has six sequential electron transfer at − 0.96 V (vs. Fc/Fc+) to produce free C60 and NO2− anion.
關鍵字Electrochemistry;C60 derivatives;Nitrated fullerenes;Hydroxylated fullerenes
語言英文
ISSN0925-9635
期刊性質國內
收錄於
產學合作
通訊作者
審稿制度
國別中華民國
公開徵稿
出版型式,電子版
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