期刊論文
| 學年 | 111 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2023-05-19 |
| 作品名稱 | Cr-doped LiNi0.5Mn1.5O4 Derived from bimetallic Ni/Mn Metal-Organic Framework as High‐Performance Cathode for Lithium‐Ion Batteries |
| 作品名稱（其他語言） | |
| 著者 | Yu-Sheng Hsiao, Jen-Hsien Huang, Ta-Hung Cheng, Chih-Wei Hu, Nian-Jheng Wu, Chi-Yun Yen, Shih-Chieh Hsu*, Huei Chu Weng, and Chih-Ping Chen |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Journal of Energy Storage 68, 107686 |
| 摘要 | Metal-organic frameworks (MOFs) have potential applications in the field of electrochemical energy storage due to their unique characteristics, such as structural diversity, tolerability, and chemical homogeneity. LiNi0.5Mn1.5O4 (LNMO) is a great cathode material due to its wide working voltage, high energy density, and excellent rate capability. In this study, bimetallic Ni/Mn-MOFs and Cr-doped Ni/Mn-MOFs have been prepared by solvothermal reaction, which can be used as the precursor for the synthesis of pristine and Cr-doped LNMOs. The results indicate that the MOF-derived LNMO has better electrochemical behavior than the sample obtained from the conventional co-precipitation route. The resulting MOF-derived LNMO exhibits a high specific capacity (SC, 132.4 mAh/g at 0.2C), good rate ability (116.5 mAh/g at 10C), and remarkable long-cycle performance (80.1 % capacity retention for 200 cycles at 4C). More significantly, the full lithium-ion batteries (LIBs) incorporated with the MOF-derived LNMO as a cathode and Li4Ti5O12 (LTO) as an anode exhibit superior energy storage properties. This finding provides an efficient strategy for preparing high-performance LNMO cathode materials. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 2352-1538 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | NLD |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/125511 ) |