期刊論文

學年 106
學期 2
出版(發表)日期 2018-04-01
作品名稱 Electronic structure of Cr doped Fe3O4 thin films by X-ray absorption near-edge structure spectroscopy
作品名稱(其他語言)
著者 Chi-Liang Chen; Chung-Li Dong; Kandasami Asokan; G. Chern; C.L. Chang
單位
出版者
著錄名稱、卷期、頁數 Solid State Communications 272, p.48-52
摘要 Present study reports the electronic structures of Cr doped Fe3O4 (Fe3-xCrxO4 (0  x  3) grown on MgO (100) substrates in the form of thin films fabricated by a plasma–oxygen assisted Molecular Beam Epitaxy (MBE). X-ray absorption near-edge structure (XANES) spectra at Cr & Fe L-, and O K-edges were used to understand the electronic structure: changes in the bonding nature, valence states, and site occupancies. Cr doping in Fe3O4 results in the change of charge transfer, crystal structure, and selective occupation of ions in octahedral and tetrahedral sites. Such change modifies the electrical and magnetic properties due to the covalency of Cr ions. The physical and chemical properties of ferrites are strongly dependent on the lattice site, ion size of dopant, and magnetic nature present at different structural symmetry of the spinel structure.
關鍵字 Thin films; MBE;Magnetite;X-ray absorption spectroscopy
語言 en
ISSN
期刊性質 國外
收錄於 SCI EI
產學合作
通訊作者 Chi-Liang Chen
審稿制度
國別 TWN
公開徵稿
出版型式 ,電子版,紙本
相關連結

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/113671 )