期刊論文

學年 99
學期 1
出版(發表)日期 2011-01-01
作品名稱 Role of 3d electrons in the rapid suppression of superconductivity in the dilute V doped spinel superconductor LiTi2O4
作品名稱(其他語言)
著者 Chen, C. L.; Dong, C. L.; Asokan, K.; Chen, J. L.; Liu, Y. S.; Guo, J.-H.; Yang, W. L.; Chen, Y. Y.; HSu, F. C.; Chang, C. L.; Wu, M. K.
單位 淡江大學物理學系暨研究所
出版者 Bristol: Institute of Physics Publishing Ltd.
著錄名稱、卷期、頁數 Supercond. Sci. Technol. 24, 115007(7pages)
摘要 The microscopic effects of V doping in LiTi2O4 have been poorly understood. The present study employs x-ray absorption near-edge structure (XANES) and resonant inelastic soft-x-ray scattering (RIXS) spectroscopy to understand the change in the electronic structure due to dilute V doping in spinel LiTi2O4 and the possible origin for the rapid suppression of superconductivity in these compounds. Results from the XANES spectra at Ti L and K edges and Ti L-RIXS show that Ti exists in a mixed-valence state and, with V doping, the unoccupied states of Ti in the t2g band increase. The rapid suppression of superconductivity is associated with the change in Ti 3d electrons and Ti–O hybridization.
關鍵字
語言 en_US
ISSN 0953-2048 1361-6668
期刊性質 國外
收錄於
產學合作
通訊作者
審稿制度
國別 GBR
公開徵稿
出版型式 紙本 電子版
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