期刊論文

學年 76
學期 1
出版(發表)日期 1987-09-01
作品名稱 High-temperature superconductivity in the presence of O 2p-Cu 3d holes: A spectroscopic study
作品名稱(其他語言)
著者 Horn, S.; Cai, J.; Shaheen, S. A.; Jeon, Y.; Croft, M.; Chang, C. L.; den Boerand, M. L.
單位 淡江大學物理學系
出版者 College Park: American Physical Society
著錄名稱、卷期、頁數 Physical Review B (Condensed Matter) 36(7), pp.3895-3898
摘要 We report core-level spectroscopic measurements of several cuprate perovskites comparing those which exhibit superconductivity above 90 K to others which do not. Both x-ray photoemission and x-ray absorption results show that in the former Cu is more oxidized, as in CuO (nominally Cu2+), than in the latter. Trivalent Cu is clearly excluded. The O 1s core level is at higher binding energy in the superconductors, implying the presence of O 2p holes. The rare-earth valence in Ce- and Pr-based perovskites is more than 3+, apparently related to their failure to superconduct.
關鍵字
語言 en
ISSN 0163-1829 1095-3795
期刊性質 國外
收錄於 SCI
產學合作
通訊作者
審稿制度
國別 USA
公開徵稿
出版型式 紙本 電子版
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